Synthesis,Film Morphology and Performance on Fabrics of a Novel Amino Functional Polysiloxane

摘要:

文章预览

A novel polysiloxane bearing (N,N)-dimethyl-γ-aminopropyl-γ-aminopropyl side groups(ASO-2) was synthesized by copolymerization of octamethylcyclotetrasiloxane with (N,N)-dimethyl-γ-aminopropyl-γ-aminopropyl methyl dimethoxysilane and hexamethyldisiloxane. Chemical structure, film morphology and the softening fabric property of ASO-2 were characterized and investigated by IR, 1H-NMR, SEM, atomic force microscope(AFM) and Kawabata evaluation system(KES).The experiment results indicate that ASO-2 can form a hydrophobic film on both the cotton fiber and silicon wafer surface. The ASO-2 film relatively exhibits a non-homogeneous structure and uneven morphology in its AFM images. Consequently, in 2 μm2 scanning field, the root mean square roughness of ASO-2 film reaches to 0.226 nm, which is 2.69 times rougher as compared with that of N-β-aminoethyl-γ-aminopropyl polysiloxane (ASO-1) film. Application experiments indicate though the tactile of ASO-2 imparted on 100% cotton is somewhat rougher than that of ASO-1, the whiteness and wettability of the cotton treated by ASO-2 are better than those by ASO-1.

信息:

期刊:

编辑:

Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He

页数:

2981-2985

DOI:

10.4028/www.scientific.net/AMR.239-242.2981

引用:

L. X. Huang et al., "Synthesis,Film Morphology and Performance on Fabrics of a Novel Amino Functional Polysiloxane", Advanced Materials Research, Vols. 239-242, pp. 2981-2985, 2011

上线时间:

May 2011

输出:

价格:

$38.00

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